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2. The Brønsted coefficients (β) for the rate-controlling steps for the enolization of acetone by the principal routes are shown to be inversely related to the magnitude of the rate constants.

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4. Rates of ketonization of the enol of acetophenone, generated by flash photolytic photohydration of phenylacetylene, were measured in aqueous sulfuric and perchloric acid solutions over the concentration range 1–50 wt.% acid; rates of enolization of acetophenone, monitored by bromine scavenging, were also measured in aqueous perchloric acid solutions over the same concentration range.